Step 1: Formula for the area of a sector.
\[
\text{Area of a sector} = \dfrac{\theta}{360^\circ} \times \pi r^2
\]
Step 2: Substitute the given values.
\[
r = 4 \text{ cm}, \, \theta = 60^\circ
\]
\[
\text{Area} = \dfrac{60}{360} \times \pi \times (4)^2 = \dfrac{1}{6} \times 16\pi = \dfrac{8}{3}\pi \, \text{cm}^2
\]
Step 3: Conclusion.
Hence, the area of the sector is $\dfrac{8}{3}\pi$ cm$^2$.