Step 1: Understanding the Concept
Since \(|\vec{a}|=|\vec{b}|=|\vec{a}+\vec{b}|=1\), squaring the last gives \(1+1+2\vec{a}\cdot\vec{b}=1\), so \(\vec{a}\cdot\vec{b}=-\frac{1}{2}\).
Step 2: Dot product and magnitudes
\(\vec{u}\cdot\vec{v}=2+5\,\vec{a}\cdot\vec{b}+2=4-\frac{5}{2}=\frac{3}{2}\).
\(|\vec{u}|^{2}=1+4+4\vec{a}\cdot\vec{b}=3\) and \(|\vec{v}|^{2}=4+1+4\vec{a}\cdot\vec{b}=3\).
Step 3: Find the angle
\(\cos\theta=\frac{3/2}{\sqrt{3}\sqrt{3}}=\frac{1}{2}\), so \(\theta=\frac{\pi}{3}\).
Final Answer:
The angle is \(\frac{\pi}{3}\).
\[ \boxed{\text{(C) }\dfrac{\pi }{3}} \]