Concept:
The dot product of two vectors is given by
\[
\mathbf{a}\cdot\mathbf{b} = |\mathbf{a}|\,|\mathbf{b}|\cos\theta
\]
where
\(|\mathbf{a}|\) and \(|\mathbf{b}|\) are the magnitudes of the vectors and
\(\theta\) is the angle between them.
Step 1: Use the given condition.
\[
\mathbf{a}\cdot\mathbf{b} = 0
\]
Substitute into the formula:
\[
|\mathbf{a}|\,|\mathbf{b}|\cos\theta = 0
\]
Step 2: Since the vectors are non-zero, their magnitudes are not zero.
\[
|\mathbf{a}| \neq 0, \quad |\mathbf{b}| \neq 0
\]
Therefore,
\[
\cos\theta = 0
\]
Step 3: Find the angle.
\[
\theta = 90^\circ
\]
Thus, the vectors are perpendicular.