Step 1: Use the sum condition:
\(\vec a = -(\vec b + \vec c)\), so \(|\vec a|^2 = |\vec b|^2 + |\vec c|^2 + 2\vec b\cdot\vec c\).
Step 2: Find cos theta:
\(9 = 9 + 9 + 2\cdot9\cos\theta\), so \(\cos\theta = -\frac12\) and \(\theta = 120^\circ\).
Step 3: Evaluate:
\(\tan^2\theta = (\sqrt3)^2 = 3\) and \(\cot^2\theta = \frac13\). So \(\tan^2\theta + \cot^2\theta = 3 + \frac13 = \frac{10}{3}\).
Final Answer:
The value is \(\frac{10}{3}\), option (D).
\[ \boxed{\frac{10}{3}} \]