Both \( \text{Ni}^{2+} \) and \( \text{Ti}^{3+} \) are coloured ions in aqueous solutions, whereas \( \text{Sc}^{3+} \) and \( \text{Cu}^{2+} \) are colourless.
Step 2: Conclusion.
Thus, the correct answer is (4) \( \text{Ni}^{2+}, \text{Ti}^{3+} \).