Concept:
According to the fundamental theorem of Linear Programming Problems (LPP), if the maximum or minimum value of an objective function \( Z = px + qy \) occurs at more than one corner point of the feasible region, then it must occur at every single point lying along the line segment connecting those two corner points.
Therefore, if all points on the segment \(AB\) yield the maximum value of \(Z\), the value of \(Z\) at point \(A\) must be perfectly equal to the value of \(Z\) at point \(B\):
\[
Z_A = Z_B
\]
Step 1: Computing the value of \(Z\) at corner point \(A(0, 3)\).
Substitute \(x = 0\) and \(y = 3\) into the given objective function equation \( Z = px + qy \):
\[
Z_A = p(0) + q(3) = 3q
\]
Step 2: Computing the value of \(Z\) at corner point \(B(3, 2)\).
Substitute \(x = 3\) and \(y = 2\) into the objective function equation \( Z = px + qy \):
\[
Z_B = p(3) + q(2) = 3p + 2q
\]
Step 3: Equating the two values to establish the relationship.
Since all points on segment \(AB\) give the maximum value, we set the two expressions equal to each other:
\[
Z_A = Z_B \implies 3q = 3p + 2q
\]
Step 4: Simplifying the equation.
Subtract \(2q\) from both sides of the equation to isolate the variables:
\[
3q - 2q = 3p \implies q = 3p
\]
Hence, the correct relation is \(q = 3p\), corresponding to option (C).