Step 1: Understanding the Question:
We are given a null vector sum equation indicating that three vectors form a closed triangle. Given the specific scalar magnitudes of each vector, we want to isolate the structural angle between vectors $\vec{a}$ and $\vec{b}$.
Step 2: Key Formula or Approach:
1. Isolate the vector $\vec{c}$ on one side of the given equation: $\vec{a} + \vec{b} = -\vec{c}$.
2. Take the self dot product (or square both sides) of the vector expression:
$$|\vec{a} + \vec{b}|^2 = |-\vec{c}|^2$$
3. Expand using the vector identity:
$$|\vec{a}|^2 + |\vec{b}|^2 + 2|\vec{a}||\vec{b}|\cos\theta = |\vec{c}|^2$$
Where $\theta$ represents the angle between vectors $\vec{a}$ and $\vec{b}$.
Step 3: Detailed Explanation:
Let's substitute the given numerical magnitudes into our expanded formula:
$$3^2 + 5^2 + 2(3)(5)\cos\theta = 7^2$$
$$9 + 25 + 30\cos\theta = 49$$
$$34 + 30\cos\theta = 49$$
Isolate the term containing $\cos\theta$:
$$30\cos\theta = 49 - 34$$
$$30\cos\theta = 15$$
$$\cos\theta = \frac{15}{30} = \frac{1}{2}$$
Since $\cos\theta = \frac{1}{2}$ within the vector angle domain $[0, \pi]$, we take the inverse cosine:
$$\theta = \frac{\pi}{3}\ (\text{or}\ 60^\circ)$$
Step 4: Final Answer:
The angle between vectors $\vec{a}$ and $\vec{b}$ is $\frac{\pi}{3}$, matching option (A).