Step 1: Understanding the Concept
All three vectors are unit vectors, so \(|\vec{a}|=|\vec{b}|=|\vec{c}|=1\). Rearrange to \(\vec{a}+\vec{c}=\sqrt{3}\,\vec{b}\).
Step 2: Square the Magnitude
\(|\vec{a}+\vec{c}|^{2}=3|\vec{b}|^{2}=3\).
Step 3: Expand
\(|\vec{a}|^{2}+|\vec{c}|^{2}+2\vec{a}\cdot\vec{c}=3\Rightarrow1+1+2\cos\theta=3\).
Step 4: Solve
\(\cos\theta=\dfrac{1}{2}\), so \(\theta=\dfrac{\pi}{3}\), option (B).
Final Answer:
The angle between a and c is pi/3.
\[ \boxed{\text{(B) }\dfrac{\pi}{3}} \]