Step 1: Understand the given curve.
The given curve is
\[
y=2^{x+2}
\]
For any point on this curve, if the \(x\)-coordinate is known, then the \(y\)-coordinate can be found using this equation.
Step 2: Find the coordinates of point \(P\).
Given,
\[
\overrightarrow{OP}\cdot \vec{i}=-1
\]
This means the \(x\)-coordinate of \(P\) is \(-1\).
So,
\[
x=-1
\]
Now, using \(y=2^{x+2}\),
\[
y=2^{-1+2}=2^1=2
\]
Therefore,
\[
P=(-1,2)
\]
Hence,
\[
\overrightarrow{OP}=-\vec{i}+2\vec{j}
\]
Step 3: Find the coordinates of point \(Q\).
Given,
\[
\overrightarrow{OQ}\cdot \vec{i}=2
\]
This means the \(x\)-coordinate of \(Q\) is \(2\).
So,
\[
x=2
\]
Now, using \(y=2^{x+2}\),
\[
y=2^{2+2}=2^4=16
\]
Therefore,
\[
Q=(2,16)
\]
Hence,
\[
\overrightarrow{OQ}=2\vec{i}+16\vec{j}
\]
Step 4: Calculate \(\overrightarrow{OQ}-4\overrightarrow{OP}\).
We have,
\[
\overrightarrow{OQ}=2\vec{i}+16\vec{j}
\]
and
\[
\overrightarrow{OP}=-\vec{i}+2\vec{j}
\]
Therefore,
\[
\overrightarrow{OQ}-4\overrightarrow{OP}
=
(2\vec{i}+16\vec{j})-4(-\vec{i}+2\vec{j})
\]
\[
=2\vec{i}+16\vec{j}+4\vec{i}-8\vec{j}
\]
\[
=6\vec{i}+8\vec{j}
\]
Step 5: Final conclusion.
Hence,
\[
\boxed{6\vec{i}+8\vec{j}}
\]