Step 1: Recall the definition of a function.
A function from a set \(A\) to a set \(B\) must assign every element of \(A\) to exactly one element of \(B\). Further, for a function
\[
f:A\to B,
\]
the image of every element of \(A\) must belong to \(B\).
Here,
\[
A=B=\{\text{positive real numbers}\}.
\]
Step 2: Check whether the image always belongs to the codomain.
Given,
\[
f(x)=3x^2-2.
\]
Take
\[
x=\frac{1}{2},
\]
which is a positive real number. Then
\[
f\left(\frac{1}{2}\right)
=3\left(\frac{1}{2}\right)^2-2
=\frac{3}{4}-2
=-\frac{5}{4}.
\]
Step 3: Verify the codomain condition.
Since
\[
-\frac{5}{4}\lt 0,
\]
the value
\[
f\left(\frac{1}{2}\right)
\]
is not a positive real number.
Thus an element of the domain is mapped outside the codomain.
Step 4: Conclude about the relation.
Because the codomain is the set of positive real numbers, every image must be positive. However,
\[
f\left(\frac{1}{2}\right)=-\frac{5}{4}
\]
is not positive.
Therefore, the given relation does not define a function from positive real numbers to positive real numbers.
Step 5: Final conclusion.
Hence,
\[
\boxed{\text{\(f\) is not a function}}
\]
and the correct option is
\[
\boxed{(4)}.
\]