Step 1: For any \(n\times n\) matrix \(A\), the standard identity for the adjoint (adjugate) matrix is \[\det(\operatorname{adj} A) = \left[\det(A)\right]^{n-1}\]
Step 2: Here \(n = 3\) and \(B = \operatorname{adj} A\), so \[\det(B) = \left[\det(A)\right]^{3-1} = \left[\det(A)\right]^2\]
Step 3: We are given \(\det(B) = 64\), so \[\left[\det(A)\right]^2 = 64\]
Step 4: Taking the square root of both sides, \[\det(A) = \pm\sqrt{64} = \pm 8\]
So the determinant of \(A\) is \(\boxed{\pm 8}\).