Question:

Identify the reagent used in Etard reaction.

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The Etard reaction converts toluene to benzaldehyde using a chromium reagent.
Updated On: Nov 12, 2026
  • \(\text{SnCl}_{2}\text{.HCl}\)
  • \(\text{CrO}_{3}\)
  • \(\text{Pd-BaSO}_{4}\)
  • \(\text{CrO}_{2}\text{Cl}_{2}\)
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the Concept
The Etard reaction oxidises the methyl group of toluene to an aldehyde group.

Step 2: Reagent
Chromyl chloride, \(\text{CrO}_2\text{Cl}_2\), is used in a solvent such as \(\text{CS}_2\) or \(\text{CCl}_4\), followed by hydrolysis.

Step 3: Match
This is the last option.

Final Answer:
The Etard reaction uses chromyl chloride, \(\text{CrO}_2\text{Cl}_2\). \[ \boxed{\text{(D) }\text{CrO}_{2}\text{Cl}_{2}} \]
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