Step 1: The principal quantum number \(n = 3\) tells us we are looking at the third shell. The azimuthal quantum number \(l = 0\) tells us we are looking only at the s subshell of that shell, which is the 3s subshell.
Step 2: For a given value of \(l\), the number of orbitals is \(2l + 1\). For \(l = 0\): \[2(0) + 1 = 1\] So the 3s subshell has just 1 orbital.
Step 3: By the Pauli exclusion principle, each orbital can hold a maximum of 2 electrons, with opposite spins. So the maximum number of electrons with \(n = 3, l = 0\) is \[1 \times 2 = 2\]
\[\boxed{2 \text{ electrons}}\]