Concept:
Several inorganic compounds are known by common names. These names are often based on their colour, source, or historical usage.
Step 1: Meaning of green vitriol.
Green vitriol is the common name of ferrous sulphate.
Step 2: Chemical identity.
Ferrous sulphate contains ferrous ion, \(Fe^{2+}\), and sulphate ion, \(SO_4^{2-}\).
\[
\text{Ferrous sulphate} = FeSO_4
\]
Step 3: Why it is called green vitriol.
Ferrous sulphate crystals are generally greenish in colour. Hence, it is commonly called green vitriol.
Step 4: Checking other options.
Copper sulphate is called blue vitriol.
Zinc sulphate is called white vitriol.
Ferric chloride is not called green vitriol.
Step 5: Final answer.
Therefore, green vitriol is chemically known as ferrous sulphate.
\[
\boxed{\text{Ferrous sulphate}}
\]