Concept:
Epsom salt is the common name of magnesium sulphate.
Step 1: Chemical identity of epsom salt.
Epsom salt is chemically magnesium sulphate.
\[
\text{Epsom salt} = MgSO_4 \cdot 7H_2O
\]
Step 2: Understanding the blank.
The question says epsom salt is sulphate. Since epsom salt is magnesium sulphate, the blank must be magnesium.
Step 3: Checking other options.
Sodium sulphate, potassium sulphate, and calcium sulphate are different salts and are not called epsom salt.
Step 4: Final answer.
Thus, chemically epsom salt is magnesium sulphate.
\[
\boxed{\text{Magnesium}}
\]