Step 1: Read the covariances directly from \(\Sigma\): \(\text{Cov}(X_1,X_2)=0\), \(\text{Cov}(X_1,X_3)=0\) and \(\text{Cov}(X_2,X_3)=-1\), with \(\text{Var}(X_1)=1\), \(\text{Var}(X_2)=4\), \(\text{Var}(X_3)=1\).
Step 2: For a jointly (multivariate) normal vector, zero covariance between two sub-vectors is equivalent to independence between them. Since \(X_1\) has zero covariance with both \(X_2\) and \(X_3\), \(X_1\) is independent of the pair \((X_2,X_3)\).
Step 3: However \(\text{Cov}(X_2,X_3)=-1\neq 0\), so \(X_2\) and \(X_3\) are NOT independent of each other. This rules out option (A), and also rules out (C) and (D) since neither \(X_2\) nor \(X_3\) is independent of the other.
Step 4: Only \(X_1\) is independent of \(X_2\) and \(X_3\).
\(\boxed{\text{Option (B)}}\)