Step 1: Understanding the Question:
The problem presents the standalone and union probabilities of two specific structural events, $A$ and $B$. We are tasked with determining the logical relationship between them from the provided classifications.
Step 2: Key Formula or Approach:
Use the Addition Theorem of Probability to calculate the probability of the simultaneous intersection of both events:
$$P(A \cup B) = P(A) + P(B) - P(A \cap B)$$
Analyze the resulting value of $P(A \cap B)$:
If $P(A \cap B) = 0$, the events are mutually exclusive.
If $P(A \cap B) = P(A) \times P(B)$, the events are independent.
Step 3: Detailed Explanation:
Let's substitute the given values into the addition theorem formula:
$$\frac{5}{6} = \frac{1}{6} + \frac{2}{3} - P(A \cap B)$$
Make the denominators uniform to combine fractions smoothly:
$$\frac{2}{3} = \frac{4}{6}$$
Now substitute back:
$$\frac{5}{6} = \frac{1}{6} + \frac{4}{6} - P(A \cap B)$$
$$\frac{5}{6} = \frac{5}{6} - P(A \cap B)$$
Isolating $P(A \cap B)$ yields:
$$P(A \cap B) = \frac{5}{6} - \frac{5}{6} = 0$$
Since the intersection probability evaluates to exactly zero, it implies that events $A$ and $B$ cannot possibly occur at the same time. Therefore, they are mutually exclusive events.
Step 4: Final Answer:
Since $P(A \cap B) = 0$, the events are mutually exclusive, corresponding to option (C).