Question:

Electronic configuration of Gd (64) is written as

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Exceptions: Gd (\(4f^7 5d^1 6s^2\)) and Lu (\(4f^{14} 5d^1 6s^2\)) have 5d\(^1\) electron.
Updated On: Apr 23, 2026
  • [Xe] \(4f^7 5d^1 6s^2\)
  • [Xe] \(4f^8 6s^2\)
  • [Xe] \(4f^9 6s^1\)
  • [Xe] \(4f^{10}\)
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The Correct Option is A

Solution and Explanation

Step 1: Understanding the Concept:
Gadolinium (Z=64) is a lanthanide. It has exceptional configuration due to half-filled f-subshell stability.
Step 2: Detailed Explanation:
Expected: [Xe] \(4f^8 6s^2\). Actual: [Xe] \(4f^7 5d^1 6s^2\).
Half-filled \(4f^7\) (7 electrons, all unpaired) is extra stable. 5d\(^1\) electron is promoted from 4f.
Step 3: Final Answer:
Thus, Gd = [Xe] \(4f^7 5d^1 6s^2\).
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