Step 1: Understand the structure of primary amines.
Primary amines are compounds where the nitrogen atom is attached to one alkyl group and two hydrogen atoms. For \( C_4H_9N \), we need to determine the different possible arrangements of the alkyl groups to form isomers.
Step 2: Draw the possible isomers.
For \( C_4H_9N \), we can have:
1. Butylamine (\( \text{CH}_3\text{CH}_2\text{CH}_2\text{NH}_2 \)),
2. Isobutylamine (\( \text{(CH}_3\text{)}_2\text{CH}\text{CH}_2\text{NH}_2 \)),
3. Sec-butylamine (\( \text{CH}_3\text{CH}_2\text{CH}(\text{CH}_3)\text{NH}_2 \)),
4. Tert-butylamine (\( (\text{CH}_3)_3\text{CNH}_2 \)).
Step 3: Conclusion.
The number of isomeric primary amines is 4, which is option (2).