For a standard linear ADC, the output code is found by \(\text{floor}( (V_{in} / V_{ref}) \times 2^N ) \), where N is the number of bits. Here, \(\text{floor}( (1.9922 / 5) \times 256 ) = \text{floor}(101.99) = 101\). Let's re-check the first method. The quantization level is \(D = V_{in}/resolution\). Okay, my first calculation was correct. 102 in decimal is 66H.