The reactions which occur in blast furnace at 500 – 800 K during extraction of iron from haematite are i. \(3Fe_2O_3 + CO \rightarrow 2Fe_3O_4 + CO_2\)ii. \(Fe_2O_3 + 3C \rightarrow 2Fe + 3CO\)iii. \(FeO + 4CO \rightarrow 3Fe + 4CO_2\)iv. \(FeO + CO \rightarrow 2FeO + CO_2\)
Evaluate the correctness of the given statements.I. Negative deviation occurs when A-B interactions are stronger than A-A and B-B. II. Reverse osmosis requires applied pressure greater than osmotic pressure.
Aqueous CuSO4 solution was electrolysed by passing 2 amp of current for 10 min. What is the weight (in g) of copper deposited at cathode? (Cu = 63 u; F = 96500 C mol-1)
50 mL of 1 M HCl was completely reacted with \(x\) g of CaCO3 to form CaCl2, CO2, and H2O. What is the value of \(x\) in g?
A few isotherms of CO2 are shown below. Identify the correct statements (Tc is the critical temperature of CO2; T1<T2<T3<Tc):I. At point X, CO₂ exists as liquidII. At point Y, CO₂ exists as gasIII. At point Z, CO₂ exists as liquid
The number of molecules having one lone pair of electrons on the central atom is from the following list: SnCl$_2$, XeF$_6$, SO$_3$, ClF$_3$, BrF$_5$, H$_2$O, XeO$_3$.
A crystalline solid of the type AB\(_2\) has a ccp arrangement for its element B. So, A occupies:
Arrange the following in increasing order of their pK\(_b\) values.
Which of the following can act as Lewis acids?[i.] \( {CCl}_4 \) [ii.] \( {GeCl}_4 \) [iii.] \( {SiF}_4 \)
The correct set of four quantum numbers for an electron in a 4d subshell is:
At 500 K, for the reaction \[ {PCl}_5(g) \leftrightarrow {PCl}_3(g) + {Cl}_2(g) \] the equilibrium constant \( K_c \) is 1.8 mol/L. What is \( K_p \) in atm at the same temperature? \[ R = 0.082 { L atm mol}^{-1} {K}^{-1} \]
A solid is dissolved in 1 L water. The enthalpy of its solution (\(\Delta H_{{sol}}^\circ\)) is 'x' kJ/mol. The hydration enthalpy (\(\Delta H_{{hyd}}^\circ\)) for the same reaction is 'y' kJ/mol. What is lattice enthalpy (\(\Delta H_{{lattice}}^\circ\)) of the solid in kJ/mol?
Identify the correct order of polarizing power of given cations:
Two statements are given below:I. SO₂ is used as antioxidant in wineII. BHA is used as food preservative in dry fruits
Two statements are given below:I. Cellulose acetate is rayonII. Perlan-L is nylon 6, 6
Adsorption of a gas on a solid obeys the Freundlich adsorption isotherm. In the graph drawn between \(\log (x/m)\) (on the y-axis) and \(\log p\) (on the x-axis), the slope and intercept are found to be 1 and 0.3, respectively. If the initial pressure of the gas is 0.02 atm, the mass of the gas adsorbed per gram of solid is (\({antilog } 0.3 = 2\)).
Acetophenone can be prepared from which of the following reactants?