Question:

Which statement is false for white phosphorus (\(P_4\))?

Show Hint

\(P_4\) has tetrahedral structure with strained \(60^\circ\) bond angles.
Updated On: Apr 16, 2026
  • It has six P–P single bonds
  • It has four P–P single bonds
  • It has four lone pairs of electrons
  • It has P–P–P angle \(60^\circ\)
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The Correct Option is A

Solution and Explanation

Concept: White phosphorus exists as \(P_4\) molecule with tetrahedral structure.

Step 1:
Bonding.
Each phosphorus atom forms three bonds with other P atoms.

Step 2:
Properties.

• Total lone pairs = 4 (one on each P atom)
• Bond angle = \(60^\circ\)

Step 3:
Conclusion.
Statement (A) is taken as false.
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