Question:

Which of the following statements is NOT true about solubility?

Show Hint

Gases that react with water, such as NH3 and CO2, do not obey Henry's law.
Updated On: Oct 1, 2026
  • The solubility of gases in water usually decreases with increase of temperature.
  • The solubility of gases in water usually increases with increase in pressure.
  • The substances having similar inter-molecular forces are likely to be soluble in each other.
  • Gases like \(\text{NH}_3\) and \(\text{CO}_2\) obey Henry's law
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the Concept:
We have to find the false statement, so we check each one.

Step 2: Check (A):
Dissolving a gas in water is exothermic, so by Le Chatelier's principle solubility drops as temperature rises. TRUE.

Step 3: Check (B):
By Henry's law, solubility of a gas is proportional to its partial pressure, so it rises with pressure. TRUE.

Step 4: Check (C):
This is 'like dissolves like'. Similar intermolecular forces allow mixing. TRUE.

Step 5: Check (D):
\(\text{NH}_3\) and \(\text{CO}_2\) react chemically with water (forming \(\text{NH}_4\text{OH}\) and \(\text{H}_2\text{CO}_3\)), so their solubility does not follow Henry's law. The statement is NOT true, so (D) is the answer.

Final Answer:
The statement that is NOT true is option (D). \[ \boxed{\text{(D)}} \]
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