Step 1: Understanding the Concept:
Natural rubber is a soft elastomer. Its chains slide over each other easily, so it is sticky and weak.
Step 2: Detailed Explanation:
In vulcanisation, rubber is heated with sulfur at 373-415 K. Sulfur forms bridges between neighbouring chains at the double bonds. These cross-links give strength, stiffness and elastic recovery.
Galvanisation is coating iron with zinc. Polymerisation builds the chains but does not specifically add cross-links to an elastomer. Hydration is the addition of water.
Step 3: Final Answer:
Vulcanisation, option (B).
Final Answer:
Vulcanisation makes sulfur cross-links in rubber.
\[ \boxed{\text{(B) }\text{Vulcanization}} \]