Step 1: Understanding the Concept
Natural rubber is an addition polymer of a diene.
Step 2: Recall the structure
Its repeating unit is isoprene (2-methylbuta-1,3-diene), and the polymer is cis-1,4-polyisoprene.
Step 3: Compare the options
Styrene gives polystyrene, butadiene is used in Buna rubber and vinyl chloride gives PVC, so the answer is isoprene.
Final Answer:
The monomer of natural rubber is isoprene.
\[ \boxed{\text{(D) }\text{Isoprene}} \]