Concept:
Freon refrigerants are chlorofluorocarbon / hydrochlorofluorocarbon compounds prepared by halogen substitution reactions of methane derivatives.
R-22 is:
$$\text{CHClF}_2$$
Its common name is chlorodifluoromethane.
Step 1: Identify precursor used industrially.
R-22 is commonly prepared from chloroform:
$$\text{CHCl}_3$$
by replacement of chlorine atoms with fluorine using fluorinating reagents such as HF.
Step 2: Why other options are less suitable?}}
- CH$_3$Cl gives different halogenated products.
- Ether is unrelated precursor.
- CCl$_4$ gives carbon tetrachloride derivatives.
- CH$_2$Cl$_2$ is not standard precursor for R-22 in this syllabus context.
Step 3: Final answer.
Thus compound used in production of freon refrigerant R-22 is:
$$\boxed{\text{CHCl}_3}$$
Hence correct option is
(A). :contentReference[oaicite:1]{index=1}