Step 1: Understanding the Concept
A positive standard reduction potential means the ion is reduced more easily than \(\text{H}^{+}\).
Step 2: Compare values
\(E^{\circ}(\text{Al}^{3+}/\text{Al})=-1.66\) V.
\(E^{\circ}(\text{Sn}^{2+}/\text{Sn})=-0.14\) V.
\(E^{\circ}(\text{Zn}^{2+}/\text{Zn})=-0.76\) V.
\(E^{\circ}(\text{Cu}^{2+}/\text{Cu})=+0.34\) V.
Step 3: Conclusion
Copper lies below hydrogen in the electrochemical series, so it has a positive value.
Final Answer:
Copper has a positive standard reduction potential.
\[ \boxed{\text{(C) }\text{Cu}} \]