Question:

Which of the following compounds is obtained when alkyl cyanides are reacted with sodium and ethanol?

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Sodium and ethanol give nascent hydrogen, which reduces the cyanide group to a primary amine.
Updated On: Nov 12, 2026
  • Primary amine
  • Secodary amine
  • Tertiary amine
  • Amide
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The Correct Option is A

Solution and Explanation

Step 1: Understanding the Concept
Sodium with ethanol produces nascent hydrogen, which is a reducing agent.

Step 2: Write the Reaction
\(\text{R-C}\equiv\text{N}+4[\text{H}]\xrightarrow{\text{Na/C}_{2}\text{H}_{5}\text{OH}}\text{R-CH}_{2}\text{NH}_{2}\).

Step 3: Compare the options
The product is a primary amine with one more carbon than the starting alkyl group. Option (A).

Final Answer:
The product is a primary amine. \[ \boxed{\text{(A) }\text{Primary amine}} \]
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