Step 1: A buffer solution consists of a weak acid/base and its conjugate salt.
Step 2:
\beginitemize
• NH₃ is a weak base.
• NH₄OH provides NH₄⁺, the conjugate acid of NH₃.
\enditemize
Step 3: Other combinations involve strong acids and strong bases which cannot form buffers.
Hence, option (A) forms a buffer solution.