Concept:
Alcohols such as ethanol contain a weakly acidic \(-OH\) group. When an active metal like sodium reacts with ethanol, sodium replaces the hydrogen atom of the hydroxyl group.
This reaction forms sodium ethoxide and releases hydrogen gas.
Step 1: Write the chemical reaction.
\[
2C_2H_5OH + 2Na \rightarrow 2C_2H_5ONa + H_2
\]
Step 2: Identify the evolved gas.
From the reaction, hydrogen atoms combine to form hydrogen gas:
\[
\boxed{H_2}
\]
Thus, the gas evolved when sodium reacts with ethanol is hydrogen gas.