Question:

Which from following compounds has lowest thermal stability?

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Stability falls as the bond becomes longer and weaker; IBr has the largest, weakest bond.
Updated On: Oct 1, 2026
  • \(\text{IBr}\)
  • \(\text{BrCl}\)
  • \(\text{BrF}\)
  • \(\text{ClF}\)
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The Correct Option is A

Solution and Explanation

Step 1: Understanding the Concept
Thermal stability of an interhalogen XX' depends on the strength of the X-X' bond. Bond strength decreases as the difference in size from the bonded atoms leads to poorer overlap and as the atoms get larger.

Step 2: Detailed Explanation
ClF, BrF and BrCl contain smaller halogens, giving shorter bonds. In IBr, the large iodine atom makes a longer bond with poor overlap, so the bond is the weakest.
The weakest bond breaks most easily on heating, so IBr is the least stable.

Final Answer:
IBr has the lowest thermal stability, option (A). \[ \boxed{\text{IBr (A)}} \]
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