Step 1: Understanding the Concept
Thermal stability of an interhalogen XX' depends on the strength of the X-X' bond. Bond strength decreases as the difference in size from the bonded atoms leads to poorer overlap and as the atoms get larger.
Step 2: Detailed Explanation
ClF, BrF and BrCl contain smaller halogens, giving shorter bonds. In IBr, the large iodine atom makes a longer bond with poor overlap, so the bond is the weakest.
The weakest bond breaks most easily on heating, so IBr is the least stable.
Final Answer:
IBr has the lowest thermal stability, option (A).
\[ \boxed{\text{IBr (A)}} \]