Step 1: Understanding the Concept
The R group (side chain) can be aliphatic, aromatic or heterocyclic.
Step 2: Check each option
Arginine has a guanidinium group (open chain). Leucine has an isobutyl group. Phenylalanine has a benzyl group (benzene, carbocyclic).
Tryptophan has an indole side chain, which contains a nitrogen atom in the ring, so it is heterocyclic.
Step 3: Match
The answer is Tryptophan, option (D).
Final Answer:
Tryptophan has a heterocyclic indole ring in its side chain.
\[ \boxed{\text{(D) }\text{Tryptophan}} \]