Concept:
The Earth's interior is divided into different layers separated by seismic discontinuities, where seismic wave velocities change abruptly due to changes in composition or physical state.
Step 1: Identify the major discontinuities.
• Conrad Discontinuity $\rightarrow$ Between the upper and lower continental crust.
• Gutenberg Discontinuity $\rightarrow$ Between the mantle and the outer core.
• Lehmann Discontinuity $\rightarrow$ Between the outer core and the inner core.
• Repetti Discontinuity $\rightarrow$ Between the upper and lower mantle.
Step 2: Locate the mantle--outer core boundary.
The boundary separating the mantle from the liquid outer core is known as the Gutenberg Discontinuity.
\[
\boxed{\text{Mantle} \longrightarrow \text{Gutenberg Discontinuity} \longrightarrow \text{Outer Core}}
\]
Therefore, the correct option is
\[
\boxed{(B)\;\text{Gutenberg}.}
\]