Concept:
For an electron accelerated through a potential difference \(V\),
\[
\lambda=\frac{h}{\sqrt{2meV}}
\]
Hence,
\[
\lambda\propto\frac{1}{\sqrt{V}}
\]
Therefore,
\[
\lambda\sqrt{V}=\text{constant}
\]
Step 1: Relate the two wavelengths.
Initially,
\[
\lambda_1=\lambda
\]
Finally,
\[
\lambda_2=\frac{2\lambda}{3}
\]
Using
\[
\lambda_1\sqrt{V_1}
=
\lambda_2\sqrt{V_2}
\]
we get
\[
\lambda\sqrt{V_1}
=
\frac{2\lambda}{3}\sqrt{V_2}
\]
\[
\sqrt{V_2}
=
\frac{3}{2}\sqrt{V_1}
\]
Squaring,
\[
V_2
=
\frac{9}{4}V_1
\]
Step 2: Calculate percentage increase.
Increase in potential:
\[
\Delta V
=
V_2-V_1
=
\left(\frac94-1\right)V_1
\]
\[
=
\frac54V_1
\]
Percentage increase:
\[
\frac{\Delta V}{V_1}\times100
=
\frac54\times100
\]
\[
=125\%
\]
\[
\boxed{125\%}
\]