Step 1: Understanding the Concept:
Coordination number is the number of nearest neighbour particles that touch a given particle in a crystal.
Step 2: Detailed Explanation:
In a simple cubic (primitive) structure, particles sit at the corners of a cube. A given particle has one neighbour in each of the six directions: left and right, front and back, up and down. So the number of nearest neighbours is 6.
Step 3: Comparison:
For comparison, bcc has coordination number 8, and fcc and hcp (both closest packed) have 12.
Step 4: Why the other options are wrong.
The value 2 (A) is characteristic of a linear chain, and 4 (B) is found in a square arrangement or in tetrahedral coordination. The value 12 (D) belongs to closest packed structures, and simple cubic is not close packed.
Final Answer:
The coordination number is 6, option (C).
\[ \boxed{6} \]