Concept:
The coordination number of a crystal structure is the number of nearest neighboring atoms surrounding a given atom.
In a Face-Centered Cubic (FCC) structure:
• Atoms are located at the corners of the cube.
• Additional atoms are located at the center of each face.
Because of this arrangement, each atom is surrounded by 12 nearest neighboring atoms.
Step 1: Understand the FCC arrangement.
In an FCC lattice, atoms are present at:
• 8 cube corners
• 6 face centers
Step 2: Determine nearest neighbors.
Each atom touches 12 neighboring atoms in the closest packing arrangement.
Step 3: State the coordination number.
\[
\boxed{\text{Coordination number} = 12}
\]