Step 1: Understand octahedral voids.
In an octahedral void, a cation is surrounded by six anions placed at the corners of an octahedron.
Step 2: Relate void type to coordination number.
The coordination number is defined as the number of nearest neighboring ions surrounding a given ion.
Step 3: Conclusion.
Since an octahedral hole is surrounded by six anions, the coordination number of the cation is \(6\).