Question:

What is IUPAC name of following compound?

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Always prioritize the double bond over alkyl or halo groups when numbering the parent carbon chain in alkenes.
Updated On: May 14, 2026
  • 1-Bromo-1,1-dimethylbut-2-ene
  • 4-Bromo-4-methylpent-2-ene
  • 2-Bromo-2-methylpent-3-ene
  • 4-Bromo-4,4-dimethylbut-2-ene
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The Correct Option is B

Solution and Explanation


Step 1: Concept

IUPAC nomenclature requires selecting the longest carbon chain containing the principal functional group (double bond) and numbering it to give the double bond the lowest possible locant.

Step 2: Meaning

The parent chain must include the alkene. Substituents like bromine and methyl groups are then identified and numbered based on their position on this parent chain.

Step 3: Analysis

The longest chain containing the double bond has 5 carbons (pentene). Numbering starts from the right to give the double bond the lower number (position 2). This places the bromine atom and the methyl group at position 4.

Step 4: Conclusion

Combining the locants and names alphabetically (Bromo before Methyl), the name is 4-Bromo-4-methylpent-2-ene. Final Answer: (B)
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