Step 1: Understanding the Concept
Friedel-Crafts alkylation puts an alkyl group on a benzene ring using an alkyl halide and a Lewis acid, anhydrous \(\text{AlCl}_3\).
Step 2: Detailed Explanation
\[ \text{C}_6\text{H}_6 + \text{CH}_3\text{Cl} \xrightarrow{\text{AlCl}_3} \text{C}_6\text{H}_5\text{CH}_3 + \text{HCl} \]
(A) with \(\text{NH}_3\) gives no such reaction. (C) with \(\text{CH}_3\text{COCl}\) is the acylation reaction, giving acetophenone. (D) methane is not an alkylating agent here.
Final Answer:
The alkylation reactants are benzene and methyl chloride, option (B).
\[ \boxed{\text{C}_6\text{H}_6 + \text{CH}_3\text{Cl}} \]