Step 1: Use the power-current relation instead of energy-charge. Electrical power is \( P = VI \), so \( V = \dfrac{P}{I} \).
Step 2: The dimensional formula of power is \( [P] = M L^2 T^{-3} \) (energy per unit time), and current has the base dimension \( [I] = A \).
Step 3: Dividing, \[ [V] = \frac{M L^2 T^{-3}}{A} = M L^2 T^{-3} A^{-1} \] which is the same result reached via energy per unit charge.