Total number of molecules/species from the following which will be paramagnetic is ………. \[ O_2, O_2^+, O_2^-, NO, NO_2, CO, K_2[NiCl_4], [Co(NH_3)_6]Cl_3, K_2[Ni(CN)_4] \]
A species is paramagnetic if it has unpaired electrons:
- \( O_2 \) (paramagnetic) ✅
- \( O_2^+ \) (paramagnetic) ✅
- \( O_2^- \) (paramagnetic) ✅
- \( NO \) (paramagnetic) ✅
- \( NO_2 \) (paramagnetic) ✅
- \( CO \) (diamagnetic) ❌
- \( K_2[NiCl_4] \) (paramagnetic) ✅
- \( [Co(NH_3)_6]Cl_3 \) (diamagnetic) ❌
- \( K_2[Ni(CN)_4] \) (diamagnetic) ❌
Total paramagnetic species = 5.
A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol$^{-1}$) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is $____________ \(\times 10^{-2}\). (nearest integer)
[Given : $K_{b}$ of the solvent = 5.0 K kg mol$^{-1}$]
Assume the solution to be dilute and no association or dissociation of X takes place in solution.