Question:

Total number of electrons involved in the formation of bridge bonds in the structure of diborane is

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Diborane has 2 bridge bonds. Each banana bond requires exactly 2 electrons, making it 4 electrons in total for bridging.
Updated On: Jun 3, 2026
  • 6
  • 2
  • 4
  • 3
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The Correct Option is C

Solution and Explanation

Step 1: Concept
Diborane ($B_{2}H_{6}$) contains two types of bonds: terminal two-center two-electron ($2c-2e$) bonds and bridging three-center two-electron ($3c-2e$) bonds.

Step 2: Meaning
A bridge bond involves three atoms ($B-H-B$) sharing a single pair of electrons, making it an electron-deficient banana bond configuration.

Step 3: Analysis
There are exactly two bridging $B-H-B$ bonds present in a diborane molecule. Since each three-center bridge bond contains $2$ electrons, the total number of electrons involved across both bridge bonds is: $2 \text{ bridge bonds} \times 2 \text{ electrons per bond} = 4 \text{ electrons}$.

Step 4: Conclusion
Thus, the total count of electrons allocated exclusively within these bridging centers is 4.

Final Answer: (C)
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