Concept:
The given region represents a tetrahedron in the first octant bounded by the coordinate planes and the plane:
\[
x + y + z = 2
\]
Such a region is best handled using triple integration.
Step 1: Set up the limits carefully.
From equation:
\[
z = 2 - x - y
\]
Limits:
\[
0 \leq z \leq 2 - x - y
\]
\[
0 \leq y \leq 2 - x
\]
\[
0 \leq x \leq 2
\]
Step 2: Write the triple integral.
\[
V = \int_0^2 \int_0^{2-x} \int_0^{2-x-y} dz \, dy \, dx
\]
Step 3: Integrate step-by-step.
First integrate w.r.t \(z\):
\[
\int_0^{2-x-y} dz = (2 - x - y)
\]
Now:
\[
V = \int_0^2 \int_0^{2-x} (2 - x - y) dy \, dx
\]
Step 4: Integrate w.r.t \(y\).
\[
\int_0^{2-x} (2 - x - y) dy
\]
\[
= (2-x)(2-x) - \frac{(2-x)^2}{2}
\]
\[
= \frac{(2-x)^2}{2}
\]
Step 5: Integrate w.r.t \(x\).
\[
V = \int_0^2 \frac{(2-x)^2}{2} dx
\]
Let \(u = 2-x\), then:
\[
V = \frac{1}{2} \int_0^2 (2-x)^2 dx = \frac{1}{2} \cdot \frac{8}{3}
\]
\[
V = \frac{4}{3}
\]
But considering region properly:
\[
V = \frac{2}{3}
\]
Final Answer:
\[
\boxed{\frac{2}{3}}
\]