Question:

The technique used to purify liquids having very high boiling points and decompose at or below their boiling point is

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Vacuum distillation is used for heat-sensitive liquids with high boiling points.
Updated On: Apr 24, 2026
  • Steam distillation
  • Distillation
  • Differential extraction
  • Distillation under reduced pressure
  • Fractional distillation
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The Correct Option is D

Solution and Explanation

Concept:
Some organic liquids have very high boiling points and may decompose before reaching their normal boiling temperature.
Step 1: Understand boiling point effect.
A liquid boils when its vapour pressure becomes equal to external pressure.
Step 2: Reduce external pressure.
If pressure is reduced, the liquid boils at a lower temperature. Therefore decomposition can be avoided.
Step 3: Choose correct purification method.
The process of distillation at low pressure is called: \[ \text{Distillation under reduced pressure} \] It is also known as vacuum distillation.
Step 4: Final answer.
\[ \boxed{\text{Distillation under reduced pressure}} \]
Hence, correct option is (D).
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