Concept:
Some organic liquids have very high boiling points and may decompose before reaching their normal boiling temperature.
Step 1: Understand boiling point effect.
A liquid boils when its vapour pressure becomes equal to external pressure.
Step 2: Reduce external pressure.
If pressure is reduced, the liquid boils at a lower temperature.
Therefore decomposition can be avoided.
Step 3: Choose correct purification method.
The process of distillation at low pressure is called:
\[
\text{Distillation under reduced pressure}
\]
It is also known as vacuum distillation.
Step 4: Final answer.
\[
\boxed{\text{Distillation under reduced pressure}}
\]
Hence, correct option is (D).