Step 1: Let the radius and angle of sector be \(r\) and \(\theta\).
The perimeter of a sector is
\[
P=2r+r\theta.
\]
Since the perimeter is constant, let
\[
2r+r\theta=P.
\]
So,
\[
r(2+\theta)=P.
\]
Hence,
\[
r=\frac{P}{2+\theta}.
\]
Step 2: Write the area of sector.
The area of a sector is
\[
A=\frac{1}{2}r^2\theta.
\]
Substitute
\[
r=\frac{P}{2+\theta}.
\]
Then,
\[
A=\frac{1}{2}\left(\frac{P}{2+\theta}\right)^2\theta.
\]
So,
\[
A=\frac{P^2}{2}\cdot \frac{\theta}{(2+\theta)^2}.
\]
Since \(\frac{P^2}{2}\) is constant, we maximize
\[
\frac{\theta}{(2+\theta)^2}.
\]
Step 3: Differentiate with respect to \(\theta\).
Let
\[
g(\theta)=\frac{\theta}{(2+\theta)^2}.
\]
Then,
\[
g(\theta)=\theta(2+\theta)^{-2}.
\]
Differentiating,
\[
g'(\theta)=(2+\theta)^{-2}-2\theta(2+\theta)^{-3}.
\]
Taking common factor,
\[
g'(\theta)=\frac{(2+\theta)-2\theta}{(2+\theta)^3}.
\]
\[
g'(\theta)=\frac{2-\theta}{(2+\theta)^3}.
\]
For maximum area,
\[
g'(\theta)=0.
\]
Therefore,
\[
2-\theta=0.
\]
Hence,
\[
\theta=2.
\]
Step 4: Final conclusion.
Therefore, the sectorial angle should be
\[
\boxed{2^c}
\]