Question:

The parameters of Unit Cell in Hexagonal Crystal System is

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Memory Tip: In Hexagonal crystal system: \[ a=b\ne c \] and \[ \gamma=120^{\circ} \] This unique \(120^\circ\) angle is the identifying feature of hexagonal lattices.
Updated On: Jun 26, 2026
  • $a=b\ne c$ & $\alpha=\beta=\gamma=90^{\circ}$
  • $a=b\ne c$ & $\alpha=\beta=90^{\circ},~\gamma=120^{\circ}$
  • $a\ne b\ne c$ & $\alpha=\beta=\gamma=90^{\circ}$
  • $a=b=c$ & $\alpha=\beta=\gamma\ne90^{\circ}$
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The Correct Option is B

Solution and Explanation

Concept:
Hexagonal crystal system has characteristic unit cell parameters.
Step 1:
In hexagonal system: \[ a=b\ne c \]
Step 2:
The interaxial angles are: \[ \alpha=\beta=90^{\circ} \] \[ \gamma=120^{\circ} \]
Step 3:

• Cubic: all sides equal
• Orthorhombic: unequal sides
• Rhombohedral: equal sides with unequal angles
Step 4:
Thus the correct parameters are: \[ \boxed{a=b\ne c,\quad \alpha=\beta=90^{\circ},\gamma=120^{\circ}} \] \[ \boxed{\text{Correct Option = (2)}} \]
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