Concept:
A \(2 \times 2\) matrix is singular if and only if its determinant is zero:
\[
\begin{vmatrix}
a & b\\
c & d
\end{vmatrix}
= ad - bc = 0
\Rightarrow ad = bc
\]
So we need to count ordered quadruples \((a,b,c,d)\) from \(\{2,3,6,9\}\) satisfying:
\[
ad = bc
\]
Step 1: Understand structure of set.
\[
\{2,3,6,9\}
\]
Prime factor forms:
\[
2=2,\quad 3=3,\quad 6=2\cdot 3,\quad 9=3^2
\]
So every product becomes:
\[
2^x 3^y
\]
Step 2: Convert condition \(ad=bc\) into exponent form.
Let:
\[
a=2^{x_1}3^{y_1},\;
b=2^{x_2}3^{y_2},\;
c=2^{x_3}3^{y_3},\;
d=2^{x_4}3^{y_4}
\]
Then:
\[
x_1+x_4=x_2+x_3,\quad y_1+y_4=y_2+y_3
\]
So we are counting balanced distributions.
Step 3: Key observation.
For \(2\times 2\) matrices, singularity occurs when rows (or columns) are proportional.
So:
\[
(a,b) = k(c,d)
\]
We check valid proportional pairs within set.
Valid proportional pairs:
\[
(2,3),(6,9)
\Rightarrow (2,3)=\frac{2}{3}(3,4)\text{ not valid directly}
\]
\[
\boxed{36}
\]