Step 1: Understanding the Concept:
Mean free path \(\lambda = \frac{1}{\sqrt{2} \pi d^2 n}\), where \(d\) = molecular diameter, \(n\) = number density.
Step 2: Detailed Explanation:
\(\lambda \propto \frac{1}{d^2}\). So mean free path is inversely proportional to the square of the diameter.
Step 3: Final Answer:
Inversely proportional to square of diameter.