Concept:
Let \(t = \sin x\). In \(\left(0, \frac{\pi}{2}\right)\), \(t \in (0,1)\).
\[
a = \frac{4}{t} + \frac{1}{1-t}
\]
Step 1: Find minimum value of \(a\) for \(t \in (0,1)\).
\[
f(t) = \frac{4}{t} + \frac{1}{1-t}
\]
\[
f'(t) = -\frac{4}{t^2} + \frac{1}{(1-t)^2} = 0
\]
\[
\frac{1}{(1-t)^2} = \frac{4}{t^2} \Rightarrow \frac{1}{1-t} = \frac{2}{t} \Rightarrow t = 2 - 2t \Rightarrow 3t = 2 \Rightarrow t = \frac{2}{3}
\]
Step 2: Minimum value.
\[
f\left(\frac{2}{3}\right) = \frac{4}{2/3} + \frac{1}{1-2/3} = 6 + 3 = 9
\]
Step 3: Conclusion.
For the equation to have at least one solution, \(a\) must be at least the minimum value of the function:
\[
a_{\text{least}} = 9
\]