Concept:
The molar heat capacity of a crystalline solid at high temperature is given by Dulong and Petit's law.
Step 1: Write the given expression.
\[
C_v=3R
\]
Step 2: Identify the law.
According to Dulong and Petit's law, the molar specific heat at constant volume for many solids is approximately:
\[
C_v=3R
\]
where \(R\) is the universal gas constant.
Step 3: Final conclusion.
Therefore, the expression \(C_v=3R\) represents Dulong and Petit's law.
\[
\therefore \text{Correct Answer is (A)}
\]